Real Madrid clinched a 3-0 victory over Getafe in their Champions League group stage match at the Santiago Bernabéu Stadium on Saturday night.
Bolívar scored his second goal in three minutes from the spot after being fouled by Sergio Ramos in the box. The Spanish international then headed home a header from Toni Kroos's corner to make it 2-0 for Real Madrid.
Getafe had earlier come back from two goals down through Diego Costa and Ángel Di María but were unable to find a way past the Spanish giants' defense.
Real Madrid moved into first place in Group D with their victory while Getafe fell behind in the table. It was a significant result as Real Madrid have now reached the quarter-finals of Europe's top club competition.
Meanwhile, Manchester United suffered a 1-0 loss to Bayern Munich in their UEFA Europa League clash at the Wanda Metropolitano stadium on Sunday.
The Red Devils started well with Cristiano Ronaldo scoring the opener in the 17th minute but they were unable to keep up with the pace of the game until the final whistle.
United's hopes of reaching the last eight of the tournament were dashed when they were held to a draw against a German side who advanced to the semi-finals.
Manchester City also lost a tough 2-1 defeat to Borussia Dortmund in their round of 16 clash at the King Power Stadium.
City's star striker Erling Haaland scored the only goal for the visitors with just four minutes remaining in the match.
It was another disappointing result for the English champions as they missed out on the opportunity to reach the final of European football's premier competition.
Overall, it was a bittersweet day for both sides as Real Madrid moved closer to securing a return trip to the European capital, while Manchester United will look to bounce back from a poor performance in their Champions League encounter.